Aqueous zinc metal batteries (AZMBs) are promising technology for low-cost and environmental-friendly safe grid-scale energy storage. Yet, challenges such as dendrite growth, hydrogen evolution, and corrosion prevent their practical application. This review provides an overall insight into the intrinsic causes of these issues and assesses novel strategies–from surface engineering and electrolyte additives to separator modification, that counteract them and enhance the long-term stability of zinc anodes.

Abstract

The increasing demand for green and clean energy harvesting and their judicious storage call for pursuing new energy storage technologies. Building better batteries has drawn significant attention to fulfilling the energy demand by delivering the stored electrical energy at the anticipated time and minimal cost. Li-ion batteries play a crucial role in transitioning to a sustainable energy landscape. However, their safety and environmental issues are of concern. Zn-based batteries provide more sustainable solutions due to their low cost, enhanced safety, and environmental benignity. Still, poor thermodynamic reversibility and stability of Zn anode in the aqueous electrolytes prevent its practical application. Significant efforts such as Zn anode surface engineering and electrolyte and/or interface modification alleviate these issues. However, in-depth studies of the root causes associated with the reversibility and stability issues of Zn electrodes are still deficient. Hence, this review focuses on the underlying causes of the major issues (dendrite, hydrogen evolution, corrosion, and passivation) associated with Zn anodes. Furthermore, we have summarized the technological advances that have been made to address these issues. Finally, some promising future directions and perspectives are provided for a further in-depth understanding of thermodynamic irreversibility and to improve the overall performance of the Zn anode.