The upcoming grid-scale energy storage desperately requires sodium-ion batteries, whose performance is largely determined by anode materials, namely hard carbon (HC). However, the microstructures and electrochemical properties of HCs are strongly precursor-dependent, and comprehensively summarizing the influence of precursor on the microstructure of HCs is thus urgently needed.

Abstract

Due to the almost unlimited resource and acceptable performance, Sodium-ion batteries (SIBs) have been regarded as a promising alternative for lithium-ion batteries (LIBs) for grid-scale energy storage. As the key material of SIBs, hard carbon (HC) plays a decisive role in determining the batteries’ performance. Nevertheless, the micro-structure of HCs is quite complex and the random organization of turbostratically stacked graphene layers, closed pores, and defects make the structure-performance relationship insufficiently revealed. On the other hand, the impending large-scale deployment of SIBs leads to producing HCs with low-cost and abundant precursors actively pursued. In this work, the recent progress of preparing HCs from different precursors including biomass, polymers, and fossil fuels is summarized with close attention to the influences of precursors on the structural evolution of HCs. After a brief introduction of the structural features of HCs, the recent understanding of the structure-performance relationship of HCs for sodium storage is summarized. Then, the main focus is concentrated on the progress of producing HCs from distinct precursors. After that, the pros and cons of HCs derived from different precursors are comprehensively compared to conclude the selection rules of precursors. Finally, the further directions of HCs are deeply discussed to end this review.